Synthesize of Poly (acrylamide-co-itaconic/TiO2) Nanocomposite for Ce(III) Sorption from Monazite Leachate
نویسندگان
چکیده
In this study, Acrylamide (AAM), Itaconic acid (IA) and nano TiO2 were copolymerized using gamma irradiation with 60Co γ-rays at a dose of 25 KGy to form poly (acrylamide-co-Itaconic acid/TiO2) (P(AAM-co-IA/TiO2)). Different compositions P(AAM-co-IA/TiO2) nanocomposites are prepared examined for Ce(III) sorption. The optimum composition is C6P(AAM-co-IA/TiO2); 61.54 AAM: 30.77 IA: 2.56 TiO2: 5.13 DAM sorption efficiency 298 K, pH 6 after 60 min 80% initial concentration 200 mgL–1. C6P(AAM-co-IA/TiO2) characterized by different physicochemical techniques. the process K equilibrium attained min. kinetics isothermal models applied. monolayer adsorption capacity 76.04 mg g–1 K. reaction follows pseudo - 2nd order kinetic mechanism. change Gibbs free energy – 4.78 kJ/mol in enthalpy 60.874 kJ/mole, i.e., spontaneous endothermic.
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ژورنال
عنوان ژورنال: Journal of Polymers and The Environment
سال: 2021
ISSN: ['1566-2543', '1572-8919']
DOI: https://doi.org/10.1007/s10924-021-02320-1